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111) In "The Man Who Knew Too Much" (Season 6, episode 22), Castiel is drunk on what?

Castiel, drunk on Purgatory souls, destroys Raphael but allows Crowley to escape. Feeling unstoppable, he declares himself the new God.

112) Who kills Kevin?

In "Holy Terror" (Season 9, episode 9), everyone's favorite prophet, Kevin, dies at tht hands of Gadreel who has been posing as Ezekiel inside Sam's body.

113) What was the name of Sam's imaginary friend?

In "Just My Imagination" (Season 11, episode 8), Sully, Sam's imaginary friend from his childhood, pops up to ask the Winchesters for help because someone is out there killing imaginary friends.

114) Originally, the Winchesters were going to be the ________.

Series creator Eric Kripke originally intended for the brothers' last name to be "Harrison" as a nod to actor Harrison Ford, because he wanted Dean to have the "devil-may-care swagger of Han Solo". However, there was a Sam Harrison living in Kansas, so the name was changed for legal reasons.

115) In "Advanced Thanatology" (season 13, episode 5), who reveals that they have become the new Death?

As the first Reaper to die after Dean killed the old Death, Billie got a promotion.

116) How are Sam, Dean & John injured at the end of Season 1?

Season 1 ends on a cliffhanger when a car accident severely injures all three Winchesters.